A saponification-triggered gelation of ester-based Zn(II) complex through conformational transformations.
نویسندگان
چکیده
Novel saponification-triggered gelation in an ester-based bis-salen Zn(II) complex (1) is described. Strategic structural modifications induced by NaOH in 1 tune the dipolar-/π-interactions leading to J-aggregation and the creation of an inorganic gel material (IGM), which has been established by photophysical, DFT and rheological studies.
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ورودعنوان ژورنال:
- Chemical communications
دوره 50 70 شماره
صفحات -
تاریخ انتشار 2014